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Reaction Family Reaction Type Isomerizations bond isomerization of olefins skeletal isomerization of hydrocarbons aldehyde-ketone rearrangement pinacol rearrangements rearrangements of epoxides rearrangement of cyclic acetals ring enlargement tetrahydrofuran derivatives dihydropyran systems Cownload rearrangement benzamine rearrangement isomerization of arenes containing functional groups skeletal isomerization of alkyl- substituted arenes isomerization of substituted heteroaromatics Fries rearrangement alkylation of arenes alkylation of phenols alkylation of aromatic amines alkylation of heteroarenes alkylation of arenes acylation of phenol and phenol derivatives acylation of heteroarenes aromatic nitration aromatic halogenation chlorination of arenes bromination of arenes aromatic iodination hydroxyalkylation of arenes oxidation with oxygen ammoxidations oxidation with peroxides reactions of alkyl hydroperoxides oxidation reactions with ammonia oxidation with ship-in-bottle systems carbocyclic ring formation Diels-Alder cycloadditions cyclopropanation anthracene formation ring closure for heterocyclic formation formation of oxygen-containing ring systems formation of nitrogen-containing ring systems Electrophilic substituting of Arenes Oxidation reactions Cyclizations xviii List of Contributors Evan J.

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RELAXATION FOR CYCLISTS n Mn Nn n Mn Nn n Mn Nn 11 14 156 12 19 248 13 32 418 14 44 648 15 72 1082 16 102 1696 17 166 18 233 19 364 20 535 21 834 22 1225 2824 23 1930 4264 24 2902 6918 25 4498 10808 26 6806 17544 27 10518 27108 28 16031 44392 69952 112452 177376 284042 449520 Table 31.

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